全文获取类型
收费全文 | 4560篇 |
免费 | 493篇 |
国内免费 | 515篇 |
专业分类
化学 | 1687篇 |
晶体学 | 149篇 |
力学 | 634篇 |
综合类 | 65篇 |
数学 | 1084篇 |
物理学 | 1949篇 |
出版年
2024年 | 3篇 |
2023年 | 33篇 |
2022年 | 50篇 |
2021年 | 77篇 |
2020年 | 90篇 |
2019年 | 77篇 |
2018年 | 76篇 |
2017年 | 106篇 |
2016年 | 133篇 |
2015年 | 96篇 |
2014年 | 209篇 |
2013年 | 298篇 |
2012年 | 241篇 |
2011年 | 268篇 |
2010年 | 238篇 |
2009年 | 308篇 |
2008年 | 324篇 |
2007年 | 326篇 |
2006年 | 265篇 |
2005年 | 317篇 |
2004年 | 287篇 |
2003年 | 200篇 |
2002年 | 194篇 |
2001年 | 160篇 |
2000年 | 142篇 |
1999年 | 146篇 |
1998年 | 128篇 |
1997年 | 116篇 |
1996年 | 79篇 |
1995年 | 81篇 |
1994年 | 69篇 |
1993年 | 64篇 |
1992年 | 75篇 |
1991年 | 40篇 |
1990年 | 30篇 |
1989年 | 32篇 |
1988年 | 30篇 |
1987年 | 27篇 |
1986年 | 22篇 |
1985年 | 9篇 |
1984年 | 12篇 |
1983年 | 6篇 |
1982年 | 11篇 |
1981年 | 14篇 |
1980年 | 4篇 |
1979年 | 20篇 |
1978年 | 12篇 |
1977年 | 6篇 |
1976年 | 8篇 |
1973年 | 2篇 |
排序方式: 共有5568条查询结果,搜索用时 15 毫秒
91.
用峰鉴别技术反相高效液相色谱法测定火锅汤料中微量吗啡 总被引:3,自引:0,他引:3
本文报道了以峰鉴别技术为定性依据的测定火锅汤料中微量吗啡的反相高效液相色谱法。本法采用改良的Stas-otto法分离提取复杂样品中的微量吗啡。由于采用峰鉴别技术,增加了定性参数,大大提高了定性方法的准确性。本法简便、快速。最低检出浓度为0.04mg/L。在数十例样品分析中,与其它仪器分析结果比照,非常符合。 相似文献
92.
A five-step model for a quality assurance system is developed for an internal quality control check. It includes the quality
control of the decomposition method and the detection method as steps belonging together. The Wickbold combustion technique
as decomposition method in combination with atomic absorption spectrometry was chosen. The vaporization of the elements mercury,
arsenic, lead, antimony and selenium is based on combustion in an oxyhydrogen flame. To check the efficiency of the analytical
system, the uncertainty of results was calculated on the basis of the "Guide to the Expression of Uncertainty in Measurement".
Received: 13 January 1997 · Accepted: 29 March 1997 相似文献
93.
94.
95.
Delenclos S. Kolinsky C. Longuemart S. Hadj Sahraoui A. Buisine J. M. 《Journal of Thermal Analysis and Calorimetry》2002,70(2):549-558
The photopyroelectric (PPE) method is proposed as a sensitive technique to study a binary mixture of liquid crystals in a
contact preparation. The photothermal signal is generated while scanning the contact preparation. The crystal-smectic A, smectic
A-nematic, and nematic-isotropic interphase boundaries are detected. The displacement of these boundaries due to the variation
of the temperature is monitored. The study of these displacements allows us to draw the complete temperature-concentration
phase diagram of a binary mixtures.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
96.
The adsorption of complexes formed by sodium, potassium, and rubidium cations with macrobicyclic ligand (kryptofix 222 with C18H36N2O6 composition) is studied as a function of the ligand concentration on a stationary mercury drop in 0.1 M solutions of corresponding sulfates and chlorides by using the differential capacitance technique. Based on the model of two parallel capacitors supplemented by the Frumkin isotherm, the adsorption parameters of studied cryptates are estimated by using the regression analysis technique. Differential capacitance curves calculated with the parameters found are compared with experimental data. The comparison of the found adsorption parameters makes it possible to reveal the effects of the nature of included cations and specifically adsorbed supporting-electrolyte anions on the adsorption behavior of cryptates under study.__________Translated from Elektrokhimiya, Vol. 41, No. 4, 2005, pp. 475–481.Original Russian Text Copyright © 2005 by Stenina, Sviridova. 相似文献
97.
E. L. Anderson M. M. Thomason H. T. Mayfield W. Bertsch 《Journal of separation science》1979,2(6):335-342
A versatile two-dimensional gas chromatograph is described, consisting of 2 separate ovens, one intermediate trap, an auxiliary inlet, and the necessary hardware to effect off-line switching according to the principle of Deans. The unit has been designed for use with high resolution glass capillary columns. The performance of individual instrumental components was critically evaluated. Results showed that low dead volume glass to metal connections were required in the manifold and detector lines to minimize extra-column effects. The mass of the intermediate trap must be low to allow rapid heating. Operational parameters are discussed and examples of some applications are shown. 相似文献
98.
99.
碘溴化银乳剂薄片颗粒的潜影分散与碘离子在颗粒中的分布有关。本文用交叉光楔曝光技术测定了由次潜影造成的潜影分散,并根据所测出的潜影分散度和乳剂的表面感光度,对内、表敏的分布作了分析。结果表明,碘离子分布在颗粒边缘的乳剂,其表面潜影分散度要比碘离子均匀分布的颗粒更甚,后者且表现出内、表敏度竞争的现象。 相似文献
100.
A delayed coincidence method, time-interval analysis (TIA), has been applied to successive – decay events on the millisecond time-scale. Such decay events are part of the 220Rn216Po (T1/2 145 ms) (Th-series) and 219Rn215Po (T1/2 1.78 ms) (Ac-series). By using TIA in addition to measurement of 226Ra (U-series) from -spectrometry by liquid scintillation counting (LSC), two natural decay series could be identified and separated. The TIA detection efficiency was improved by using the pulse-shape discrimination technique (PSD) to reject -pulses, by solvent extraction of Ra combined with simple chemical separation, and by purging the scintillation solution with dry N2 gas. The U- and Th-series together with the Ac-series were determined, respectively, from alpha spectra and TIA carried out immediately after Ra-extraction. Using the 221Fr217At (T1/2 32.3 ms) decay process as a tracer, overall yields were estimated from application of TIA to the 225Ra (Np-decay series) at the time of maximum growth. The present method has proven useful for simultaneous determination of three radioactive decay series in environmental samples. 相似文献